Supports both water and dst method for factor determination. There is a good agreement between the two oven methods for wet pet food. Astm d6304 20 standard test method for determination of. Kam moisture analyzers incorporate the coulometry principle applied to karl fischer titration to totally eliminate the troublesome procedures involved in. This test method also covers the indirect analysis of water thermally removed from samples and swept with dry inert gas into the karl fischer titration cell. The determination of moisture by the volumetric method was based on aquametria with reagent karl fischer. Pdf moisture content analysis of metal powders, using oven. From literature studies on the kf titration method for water determination, information from the manual and knowledge from previous studies. Abstract the karl fischer kf titration is a method of determining the water content of solid, liquid and gaseous samples.
Each method offers an easy way to execute the tests and delivers results quickly. It is the technique preferred for use in industrial quality control. During the determination the iodide is oxidized to iodine at the anode of the generator electrode. Among all, moisture analyzers employed with heating method is easy to handle with its good operability and clear formula of operation, low profile and can be run and maintained at a low cost, which contribute to attracting a wide range of users who test many kinds of samples. Karl fischer water determination moisture contents. The karl fischer kf titration is a method of determining the water content of solid, liquid and gaseous samples. It is particularly important in marine and truck custody transfer applications where small inaccuracies can equate to large. Special focus has been put into system configuration, optional parts, and various samplers hoping that it will aid customers when selecting parts and samplers.
Mettler toledo titrators offer a broad range of possibilities to handle your data. Karl fischer moisture determination schoffski major reference. It was invented in 1935 by the german chemist karl fischer. Looking back on half a century of experience in karl fischer titration, metrohm has shaped what coulometric and volumetric water analysis are today. Moisture analysis of metal powder samples by karl fischer. Hi90302 karl fischer volumetric titrator for moisture. Karl fischer moisture analyzer 129a adarsh industrial estate, sahar road, chakala, andheri east. Introduction of karl fischer coulometric titrator with singlechamber electrolysis method koji kitanaka 1.
History of karl fischer titration the milestones 1980 changed the world of kf titration 8 1935 karl fischer published a reagent for water determination consisting of iodine, so2, pyridine and methanol 1979 eugen scholz and helga hoffmann, riedelde haen, replaced pyridine by imidazole and invented hydranal reagents. The most commonly used methods for for testing plastics and polymers using either a moisture analyzer or karl fischer titration, respectively. Karl fischer titration allows the quantification of freely available water which has been brought. Karl fischer titrators for water moisture determination. Mitsubishi compact karl fischer moisture meter cakf31. Loss of weight and karl fischer s chemical reaction. Methods measurement method measuring range applications interfering substances karl fischer titration a few ppm 100% gases,liquids, solids oxidizing,reducing substances drying 0. Karl fischer titration is a wellestablished method to measure the water content of samples. Optimization of modified moisture measurement with karl fischer to. Titration method coulometric karl fischer titration electrolysis control patented ace control system gb2370641 end point detection ac polarisation end point indication visual display print out acoustic beep display 40 character alphanumeric backlit lcd measuring range 1. History of karl fischer titration karl fischer march 24, 1901 april 16, 1958 was a german chemist published a method in 1935 to determine trace amounts of water in samples.
Liquids can usually be injected right into the instrument and gasses can be analyzed with karl fischer units specially designed to analyze gases. Moisture analysis in lotion by karl fischer coulometry. In principle it involves the oxidation of sulfur dioxide by iodine, in the presence of water, in a buffered solution. Moisture loss on drying although it is commonly known and widely accepted that karl fischer titration provides the most accurate measurement of water in feed, the labor both time and training, reagent, and instrument costs make karl fischer analysis an economic. Karl fischer water titrationprincipal component analysis. Because these analyzers work with infrared or microwave radiation to remove the moisture from a sample, they take only a few minutes to deliver a reading of the moisture result. Sample dilution method for the kam kf karl fischer moisture analyzer viscous crudes may cause difficulty with sample extraction. Karl fischer moisture analysis for measuring water in crude oil. This monograph first describes the basics of karl fischer titration. Moisture loss on drying although it is commonly known and widely accepted that karl fischer titration provides the most accurate measurement of water in feed, the labor both time and training, reagent, and instrument costs make karl fischer analysis an economic burden that most laboratories would not be willing to bear. A wide variety of karl fischer moisture analyzer options are available to you, such as power, usage, and customized support. Determination of water content using volumetric karl fischer titration is based on the stoichiometric reaction between the components of the reagent and moisture. Measurement results are convert ed to pdf and can be stored in a. There are two methods based on the use of karl fischer reagents, or karl fischer titration, to measure moisture content.
Reagent grade, suitable for karl fischer analysis karl fischer titration is a fast, precise test that can determine 0. The determination of water content moisture is one of the most frequently done tests in laboratories today. As described below, this method can be used in both volumetric and coulometric titration systems. Discover how our products can help you solve your analytical challenges. For a coulometric karl fischer titration a modified kf reagent which contains iodide is used. Here, the specific reaction of water to a karl fischer reagent is used which contains iodine, sulphur. Besides, the offered digital karl fischer moisture analyzer are provided at competitive prices to the clients. Karl fischer reagent for moisture aquamicron nittoseiko. Moisture in percentage amounts is monitored as a specification in commercial food production. Karl fischer reagent consists of iodine, sulfur dioxide, a base and a solvent, such as alcohols. This method detects only water, contrary to loss on drying, which detects any volatile substances. Lineup of moisture meter optional units this guide book is designed to introduce our moisture meter for easy understanding of the system. Automated water content determination with the 874 oven.
Single stabilized solution, preferably nonpyridine based. Kf or kft it remains the primary method of water content determination used worldwide by. Heat sample in a crucible, evaporate the moisture and transfer the vapor into the titration cell by a dry purge gas. A practical alternative to karl fischer titration for.
Today, the titration is done with an automated karl fischer titrator. The hi90302 combines an ultrahigh precision titrant delivery system with optically regulated magnetic stirring, sophisticated endpoint determination, dynamic dosing and background drift. These methods include the karl fischer titration, the infrared spectroscopy, the microwave spectroscopy, etc. Karl fischer moisture titrator ca310 series nittoseiko. The kf method is one of the few techniques that will measure water content and not be affected by other volatiles. For enquiries contact monita industrial corporation. The moisture content was estimated based on the amount of reagent with its correction factor required to hold the water in the rate of the sample tested. Karl fischer moisture analysis can be conducted on solids, liquids and even gasses. There are many applications where trace moisture measurements are necessary for manufacturing and process quality assurance. Moisture analysis covers a variety of methods for measuring moisture content in both high level and trace amounts in solids, liquids, or gases.
Introduction of karl fischer coulometric titrator with. It covers not only the kf reagents, chemical reactions, volumetric and coulometric titration as well as the different detection methods, but also deals with aspects such as interfering side reactions and sample preparation techniques. The hi90302 karl fischer volumetric titrator for moisture analysis is an extension of hannas highly successful potentiometric titrator platform. Advantages and limitations of karl fischer titration news medical. Youden analysis of karl fischer titration data from an interlaboratory study determining water in animal feed. Karl fischer moisture determination schoffski major. Introduction of karl fischer coulometric titrator with single. Manual volumetric kf titration requires reloading for each determination and hence has a high solvent consumption. Pdf moisture content analysis of metal powders, using. Water dissolved and free tan total acid number oxidation. It is a process based on the reaction of iodine with water. As pure peg solvent is a colorless sample, it was also analyzed using original method. Standard was analyzed for five times, giving an average value of 0. Mar 29, 2018 moisture analysis to karl fischer, or not to karl fischer.
Combined titrator for potentiometric karl fischer titrations for accurate moisture estimation. Water is determined by using commercially available standard karl fischer reagent integrated with a drying oven. Karl fischer titration is a classic titration method in chemical analysis that uses coulometric or volumetric titration to determine trace amounts of water in a sample. Pdf this introduction will cover the basics of the karl fischer titration. Karl fischer kf titration is a technique for the determination of moisture content. Introduction watercontent analyzers based on the karl fischer kf coulometric titration method allow accurate measurement of trace water content on the order of micrograms by exploiting the following advantages. Analysis for solutions karl fischer moisture meter guide vol. An accurate method for determining the amount of water is the karl fischer titration, developed in 1935 by the german chemist whose name it bears.
Pdf on oct 1, 2018, pelle mellin and others published moisture content analysis of metal powders, using oven desorption followed by karl fischer titration find, read and cite all the research. Karl fischer titration to determine the water content, both, the volumetric and the coulometric technique can be combined with an oven. A practical alternative to karl fischer titration for water. Karl fischer moisture analysis determining water content is a cmc requirement for pharmaceuticals and karl fischer titration is the most common way to determine water content for most drug products. Applying usp to your moisture determination lab and. Karl fischer moisture in oil test set, type kflab mkll highvolt. Kam kf karl fischer moisture analyzer user manual kam controls. The drying cabinet method to determine the material moisture the karl fischer titration to determine the water content all other methods have to be adapted to one of the two methods, if necessary. For comparison, the original hydranal moisture test kit method was tried out. Karl fischer moisture meter guide vol a1 envirosciences. It covers not only the kf reagents, chemical reactions, volumetric and coulometric titration as well. A wide variety of automatic karl fischer moisture analyzer options are available to you, such as certification, warranty, and customized support. Karl fischer titration is a fast, precise test that can determine 0. Supplied with detailed instruction and report of analysis with exact water content liquid standards are packaged in glass ampoules.
There are slight differences detected between the oven methods and karl fischer method for two of the six wet pet foods analyzed. Mercaptan, sulfide s or h 2 s, sulfur, and other compounds are known to interfere with this test method see section 6. Reagent grade, suitable for karl fischer analysis karl fischer moisture analyzer user manual per iso 12937, astm d 4928, api mpms 10. Evaluation of analytical methods for analysis of dried. Determine the exact moisture content of each lot by drying 5 g for four hours in a vacuum oven at 150 c theoretical value 15. It is performed on solids, liquids, fuels, biomass, foods, plants, soils, or just about any substance you can think of. Karl fischer published a reagent for water determination consisting of iodine, so2, pyridine.
Karl fischer moisture titrator coulometric titration equipements. Pdf water determination by karl fischer titration researchgate. Karl fischer kf determination of water with kf drying. Moisture analyzers karl fisher moisture analyzer exporter. The fluidscan is a handheld device that offers a practical solution for maintaining the key parameters of a healthy lubrication system without the need for a laboratory. Simple modification of karlfischer titration method for. Optimizing moisture testing by karl fischer method aoac. The precision statement of this method covers the nominal. During the drying process in a halogen moisture analyzer, the sample absorbs the infrared radiation of a halogen lamp. Kf titration for moisture analysis with over half a century of experience in karl fischer titration, metrohm has defined what coulometric and volumetric water analysis are today.
This video is about the determination of moisture water contents in the pharmaceuticals by using different methods and apparatus. Although usp discusses reagent formulation, commercially available karl fischer instrumentation and reagents are suitable to use. The new karl fischer moisture meter model kf31 is equipped with a buret for volumetric. Special focus has been put into system configuration, optional parts, and.
For most solids, the product should be dissolved in methanol first. The use of trade names or commercial products are examples only, and any equivalent products may be substituted. Water determination by karl fischer titration metrohm. Our groundbreaking innovations and a strong commitment to quality and precision, led to the development of a range of instruments to cover any water determination need. Kam moisture analyzers also detect cooling water leaks before they become severe enough to damage equipment. Comparison of methodologies for moisture determination on. Water determination by karl fischer titration labicom. With over half a century of experience in karl fischer titration, metrohm has defined what coulometric and volumetric water analysis are today.
Electrolysis cell of coulometric moisture meter sample injection port detection electrode coulometric titration with coulometric. In cases where the viscosity of the sample is such that it cannot be pulled into a syringe, users may dilute the sample prior to determination. To obtain reliably reproducible and traceable results, these analyzers should be aligned with your existing reference method oven drying karl fischer titration. The karl fischer titration is concerned with the determination of water. Its function can meet widely the requirements of development and research of high schools and scientific research institutions and quality control of products of.
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